Styrene/methyl methacrylate (St/MMA) copolymer-silica nanocomposite foams were prepared using supercritical CO2 as blowing agent, and the relationships between their cellular microstructure and mechanical properties
were investigated. The effects of nanosilica content, size, and surface chemistry on the foam's microstructure and properties were examined. Dispersion and distribution of silica nanoparticles with different surface chemistry in St/MMA copolymer nanocomposites were discussed. To determine the most suitable copolymer composition for incorporating silica nanoparticles, some operating conditions such as temperature and pressure were primarily examined to study their effects on the microstructure of resulting foams. In compressive mechanical properties of final foams, a considerably high value was obtained for the compressive strength of the foams of up to 9.5 MPa. The prepared low-density (below 0.2 g/cm3
) St/MMA copolymer microcellular foams can be used in
green lost foam iron casting processes.