16 اردیبهشت 1403
حبيب اعتمادي

حبیب اعتمادی

مرتبه علمی: دانشیار
نشانی: بناب - دانشگاه بناب
تحصیلات: دکترای تخصصی / مهندسی شیمی - مهندسی پلیمر
تلفن: 04137745000
دانشکده: دانشکده فنی و مهندسی
گروه: گروه مهندسی پلیمر

مشخصات پژوهش

عنوان
The effect of modified silica nanoparticles on the polycarbonate thin-film nanocomposite membranes in a submerged membrane system for the treatment of surface-contaminated water
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
Thin-flm nanocomposite membranes · Polycarbonate · Polyvinyl alcohol · Aminated silica nanoparticles · Water treatment
پژوهشگران همایون خضرآقا (نفر اول)، حبیب اعتمادی (نفر دوم)، مهدی سلامی کلجاهی (نفر سوم)، الهام شکری (نفر چهارم)

چکیده

In this study, thin-flm nanocomposite (TFN) membranes were fabricated using synthetic silica nanoparticles that had been aminated by 3-aminopropyltriethoxysilane (APTES). The modifed silica nanoparticles with APTES were analyzed using FTIR and TGA. Through the use of FTIR-ATR spectroscopy, FESEM, AFM, and water contact angle, the fabricated TFN membranes were analyzed and evaluated. All membranes were used in a submerged membrane system to remove humic acid (HA) under various transmembrane pressure (TMP) conditions at 0.4 and 0.6 bar. The outcome of the research showed that the polycarbonate (PC) support membrane has a water contact angle of 77.5°; however, the TFN membrane, which includes 0.1 wt.% of hydrophilic modifed silica nanoparticles, has a substantially lower contact angle value (55.33°). The formation of a thin layer of polyvinyl alcohol (PVA) on the PC support membrane and the proper distribution of SiO2-NH2 nanoparticles with a thickness of 93.72 nm were confrmed by FESEM images. The rejection rate for thin-flm composite (TFC) membranes was about 98.3%, while for TFN membranes, in the presence of SiO2-NH2 nanoparticles, it reached 99.2%.